The documentation for the rak19001 in the tables; pinout of the 40-pin MCU module connector anddefinition of each pin of the WisBlock Core connector: they mention that pin 16 corresponds to led 3 but the schematic indicates that it is IO8.
Both is correct, originally there were plans for a third LED controlled by GPIO IO8 from the Core module.
But IO8 is not available on any of the WisBlock Core modules, so it is not used.